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Las Primeras mujeres que pasaron a Nueva España
I came across this link that lists the first Spanish women to come to Mexico (Nueva España) during the first quarter of the XVI century. It was written by Juan Francisco Maura, Associate Professor in Spanish at the University of Vermont.
http://parnaseo.uv.es/Editorial/Maura/ConclusionYapendices.pdf
I wasn't able to add it to the links section.
Maria